If you have a use-case where you want to capitalize the first letter of each word in a text or a file using Notepad++ you may make use of the Convert case to option under Edit,
- Open your file in Notepad++ (or copy the text in a tab),
- Select the text,
- Now go to Menu: Edit -> Convert Case to,
- Select Proper Case
You would see that your text is converted with first letter of each word in upper case.

this is a demo line.
After:
This Is A Demo Line.
You can also make use of the Keybord Shortcut: Alt + U
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