If you have installed Homebrew (brew) on macOS Big Sur and did not set its PATH variable, then you may not be able to run it (unless you are in the dir where its installed) and you would get an error like zsh brew command not found,
The location where brew gets installed in macOS Big Sur is /opt/homebrew/bin/
code2care@mac bin % pwd
/opt/homebrew/bin
code2care@mac bin % ls
brew
code2care@mac bin %

Brew installation location
✏️ Article: How to fix command not found brew (bash, zsh) on macOS Terminal
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